(A Peer Review Journal)
e–ISSN: 2408–5162; p–ISSN: 2048–5170


Pages: 910-913
J.T. Ugye*, S.P. Malu, P.A. Egwaikhide and T.M. Maigari

keywords: Characterization, clay, oxides, physcio-chemical, spectrometry, x-ray


Physico-chemical and X- Ray Fluorescence (XRF) analyses was used to characterize the clay deposits from Puje ward of Wukari, Taraba State with the view to establishing its suitability for industrial usage. The physical parameters considered were moisture content, bulk density, particle density. pH and loss on ignition. Chemical analysis was performed using X-ray fluorescence spectrometry. The result of the physical analysis showed a moderate moisture content of 4.08±02%, bulk density of 1.56±16 g/cm3, pH of 7.68±01 and loss on ignition of 13.18±32%. The result of the chemical analysis showed an elemental composition in the clay samples of 54.68±12% (SiO2) > 6.50±03% (Al2O3) > 1.896±01% (Fe2O3)> 0.98±22% (K2O) as the major components while the minor components included P2O5, SO2, CaO, TiO2,V2O5,Cr2O3, MnO, CoO, CuO ,ZnO,PbO,WO3,Au2O3, Rb2O, Nb2O5, MoO2, SnO,Sb2O5and ZrO2.The results of the physical parameters were found to be within the acceptable limits in comparison with the results of WHO, APHA and US Geological Agency. Also due to the high silica content of the clay deposits as shown in the results it can be inferred that the Puje - Wukari clay deposits could be used as source of silica for the production of floor tiles, ceramics, building bricks and in the synthesis of zeolite, glass, cement, lubricants and paints.


Ahmed KS &OnajiPB 1986.The effect of Beneficiation on the properties of some Nigerian Refractory Clays.J. Nig. Soc. Chem. Engr., 6(2): 119-129. Alkan M, Demirbas O &Celikeapa S 2004.Sorption of acid red 57from aqueous sodium into sepiorite.Journal of Hazard Material, 116-135. Ahmedna M, Johnson M, Clarke SJ, Marshall WE & Reo RM 1997.Potential of agricultural by‐product‐based activated carbons for use in raw sugar decolourisation, pp. 1-17. APHA 1993.Standard methods for the examination of water and waste water, 16th Edition, American Public Health Association, Washington DC 2005. Barbell S &Kurnianwan TA 2013.Journal of Hazardous Materials, 97: 219. BreckDW 1974. Zeolite Molecular Sieve Structure, chemistry and Uses. Wiley Interscience (New York) USA, 2: 19-22. Costanzo PM 2001. Data and industrial minerals, including clay and clay mineral deposits.Journal of Clay & Clay Materials, 59(5): 372-373. Cooper D &Golledge G (Eds). 2017. Zirconia-Royal society of chemistry. Retrieved 25-04-2017,pp. 1-20. http://media.rsc.org/Zinc%20and%20zirconia/Zirconia.pdf. Edah AO, Kolawole JA, Solomon AO, Shamle N &Awode AU 2012. J. Res. Envtal. Sci. &Techn., 1(2): 19-22. Foley NK 1999. Environmental Characterization of Clays and clay mineral deposits.USGS Information handout September.US.Geoligical Survey. Vol. 954. National Center Reston, VA20192. Holtz RD & Kovacs WD 1981.An introduction to Geochemical Engineering.Chapter 4. Prentice-Hall, pp. 30-36. Huerta-Pujol O, Soliva M, Martinez-Farre FX, Valero J & .Lopez M 2010. Bulk density determination as a single and complementary tool in composting process control, pp. 205-209. MaluSP, Andrew C &Malu FI 2013. Chemical characterization of clay deposit in Taavaan, North- Central Nigeria.World Res. J. Chem., 1(2): 31-34. McGraw Hill 1992.Encyclopaedia of Science and Technology.Mc-Graw-Hill Book Company.8th Edition, 3: 752-751. Neuwirthová L, Matějka V, Kutlákováa K &Tomášek V 2012.X-Ray Fluorescence Spectrometry Analysis of Clay/Zno Composites.NanoCom. 23. - 25. 10. 2012, Brno, Czech Republic, EU, pp. 1-6. Nnuka EE &Enejor C 2001.Characterization of Nahuta clay for industrial and commercial application.Nig. J. Engr. & Materials, 2(3): 9-12. OwaborCN, Agarry SE &Jato D 2012. Removal of naphthalene from aqueous system using unripe orange peel as adsorbent: Effects of operating variables. Desalination and Water Treatment, 48(1): 315-319. PubChem 2015. Open Chemistry data base. Zinc Oxide. Retrieved 2017-04-22; https://pubchem.ncbi.nlm.nih.gov/compound/zinc_oxide Shichi T & Takagi K 2000.Photochem.Photobiol.CPhotochem. Rev., 1:113. Sidhu& Gosh, 1996.Clay Res. 15. Stevens J & Anderson S 1996. Clays. Clay Miner, 44: 132. Sreeramulu US 2003. Principles in the quantitative analysis of water, fertilizer, plants and soils.Scientific Publishers India, 2: 230-237. Uribe A 2001. Solidification, Stabilization of hazardous waste using organophilic clays.Master of Science Thesis.University of Cincinnati, Cincinnati, Ohio. USAGS 2017. Data on industrial minerals, including clay and clay mineral deposits, are available from the USGS web site, http://minerals.er.usgs.gov/minerals/pubs/commodity Velde B 1995. Composition and mineralogy of clay materials. In: Velde B (ed). Origin and Mineralogy of Clays. New York, Springer-Verlag, pp. 8-42. WHO 1971. International Standards for Drinking Water, 3rd Edition, WHO, Geneva